AdvancedTopic 88 of 100Materials & Chemical
Mass transfer
Diffusion and convection of species between phases.
In depth
Mass transfer is the movement of species by diffusion and convection: flux N=k_c(C_s-C_∞); overall coefficients from two-film theory 1/K=1/k_G+H/k_L. Correlations with Sherwood number Sh=f(Re,Sc). Governs absorption, extraction, drying, membranes and heterogeneous reactions.
Key points
- Fick's law
- Two-film model
- Analogy with heat transfer
ExampleOxygen transfer rate limits growth in aerobic fermenters.
What is Mass transfer?
Diffusion and convection of species between phases.
Why is it important to understand mass transfer?
Mass transfer limits many chemical processes, so knowing when it controls the rate prevents a poorly designed reactor or column.
What is the mass transfer coefficient?
A number that relates the mass flux to the concentration difference across the boundary, and it depends on flow and geometry.
When does mass transfer limit the rate?
When transport to or from the reaction surface is slower than the reaction itself, so faster mixing or more area raises the overall rate.
How is Mass transfer used in practice?
Typical applications include estimating the rate of gas absorption into a liquid in a packed column, checking whether mixing is limiting a gas-liquid reaction and designing a membrane contactor for oxygen transfer in a bioreactor.
What should I learn before Mass transfer?
Study "Residence time distribution" first (topic 87 of 100 in Materials & Chemical). It covers the groundwork this topic builds on.
What are the key points of Mass transfer?
Fick's law. Two-film model. Analogy with heat transfer.
Can you give an example of Mass transfer?
Oxygen transfer rate limits growth in aerobic fermenters.
What comes after Mass transfer?
The next topic is "Fluid handling in plants", which builds directly on this one.
How difficult is Mass transfer?
It is classed as Advanced in Materials & Chemical (topic 88 of 100). It is an advanced topic. It assumes you are comfortable with the intermediate topics in Materials & Chemical.