IntermediateTopic 66 of 100Materials & Chemical
Energy balances in processes
Account for heat of reaction, sensible heat and work.
In depth
Energy balance includes sensible heat, latent heat, heats of reaction and work: ΔH=Q-W_s for steady open systems. Use enthalpy of formation or heat of combustion; adiabatic reactor temperature rise; heat integration reduces utility cost.
Key points
- Reference states
- Hess's law
- Heat capacity polynomials
ExampleA reactor's cooling duty equals heat released by reaction minus enthalpy to heat the products.
Energy balances in processes show how much heat must be added or removed, which sets the sizes of heaters, coolers and boilers.
What is Energy balances in processes?
Account for heat of reaction, sensible heat and work.
Why is it important to understand energy balances in processes?
Energy balances in processes show how much heat must be added or removed, which sets the sizes of heaters, coolers and boilers.
What terms appear in a process energy balance?
Enthalpy flows in and out, heat added or removed, shaft work, and changes in kinetic and potential energy when they matter.
What is heat of reaction?
The enthalpy change when a reaction occurs at constant pressure, which tells you whether the process must be heated or cooled.
How is Energy balances in processes used in practice?
Typical applications include sizing a reboiler for a distillation column, calculating the cooling duty of a reactor exothermic reaction and estimating the heat needed to warm a feed stream to reaction temperature.
What should I learn before Energy balances in processes?
Study "Material balances" first (topic 65 of 100 in Materials & Chemical). It covers the groundwork this topic builds on.
What are the key points of Energy balances in processes?
Reference states. Hess's law. Heat capacity polynomials.
Can you give an example of Energy balances in processes?
A reactor's cooling duty equals heat released by reaction minus enthalpy to heat the products.
What comes after Energy balances in processes?
The next topic is "Unit operations", which builds directly on this one.
How difficult is Energy balances in processes?
It is classed as Intermediate in Materials & Chemical (topic 66 of 100). It is an intermediate topic. Work through the beginner topics in Materials & Chemical first.