AdvancedTopic 75 of 100Materials & Chemical
Liquid-liquid extraction
Uses a solvent to separate components.
In depth
A solvent immiscible with the feed extracts a solute by selective solubility; distribution coefficient K=y/x guides solvent choice. Equipment: mixer-settlers, columns. Use ternary diagrams to design. Suits heat-sensitive or close-boiling mixtures and pharmaceuticals.
Key points
- Raffinate and extract
- Selectivity
- Solvent recovery
ExampleCaffeine is extracted from coffee using supercritical CO₂ or ethyl acetate.
What is Liquid-liquid extraction?
Uses a solvent to separate components.
Why is it important to understand liquid-liquid extraction?
Liquid-liquid extraction separates components that cannot be distilled easily, such as heat sensitive or close boiling compounds.
What is the partition coefficient?
The ratio of concentrations in the two liquid phases at equilibrium, which determines how much solute goes into the extract.
What makes a good extraction solvent?
High selectivity for the target, low solubility in the feed liquid, easy recovery, and low cost and hazard.
How is Liquid-liquid extraction used in practice?
Typical applications include recovering a pharmaceutical from a fermentation broth using a solvent, removing acetic acid from water with an organic solvent and separating metals in hydrometallurgy using a selective extractant.
What should I learn before Liquid-liquid extraction?
Study "Absorption and stripping" first (topic 74 of 100 in Materials & Chemical). It covers the groundwork this topic builds on.
What are the key points of Liquid-liquid extraction?
Raffinate and extract. Selectivity. Solvent recovery.
Can you give an example of Liquid-liquid extraction?
Caffeine is extracted from coffee using supercritical CO₂ or ethyl acetate.
What comes after Liquid-liquid extraction?
The next topic is "Adsorption", which builds directly on this one.
How difficult is Liquid-liquid extraction?
It is classed as Advanced in Materials & Chemical (topic 75 of 100). It is an advanced topic. It assumes you are comfortable with the intermediate topics in Materials & Chemical.