BeginnerTopic 15 of 100Materials & Chemical
Phase diagrams
Maps of phases present at given temperature and composition.
In depth
Phase diagrams plot equilibrium phases against temperature and composition. Features: liquidus, solidus, solvus, eutectic, peritectic, eutectoid. Use them to predict phases, compositions and microstructure after slow cooling. Binary isomorphous (Cu-Ni), eutectic (Pb-Sn) are classic.
Key points
- Gibbs phase rule
- Tie lines
- Invariant reactions
ExampleSolder Pb-Sn eutectic melts sharply at 183 °C.
What is Phase diagrams?
Maps of phases present at given temperature and composition.
Why is it important to understand phase diagrams?
Phase diagrams show which phases exist at each temperature and composition, which tells you what microstructure an alloy will have.
What does a phase diagram show?
The phases that are stable at each temperature and composition at equilibrium, along with the boundaries between phases.
Why do real alloys differ from the diagram?
Cooling is often faster than equilibrium, so non-equilibrium phases and segregation can form.
How is Phase diagrams used in practice?
Typical applications include predicting the phases present in a brass casting at room temperature, selecting a solder composition that melts at a suitable temperature and designing a heat treatment that forms the desired phase mix in an alloy.
What should I learn before Phase diagrams?
Study "Recovery, recrystallisation and grain growth" first (topic 14 of 100 in Materials & Chemical). It covers the groundwork this topic builds on.
What are the key points of Phase diagrams?
Gibbs phase rule. Tie lines. Invariant reactions.
Can you give an example of Phase diagrams?
Solder Pb-Sn eutectic melts sharply at 183 °C.
What comes after Phase diagrams?
The next topic is "Lever rule", which builds directly on this one.
How difficult is Phase diagrams?
It is classed as Beginner in Materials & Chemical (topic 15 of 100). It is an entry-level topic. It relies only on basic school mathematics and the ideas introduced earlier in this discipline.